| Home | Away | Total | |||||||||||||
| Clubs | P | W | D | L | W | D | L | W | D | L | F | A | +/- | Pts | |
| 1 | FC Bayern München | 2 | 1 | 0 | 0 | 1 | 0 | 0 | 2 | 0 | 0 | 4 | 0 | 4 | 6 |
| 2 | SSC Napoli | 2 | 1 | 0 | 0 | 0 | 1 | 0 | 1 | 1 | 0 | 3 | 1 | 2 | 4 |
| 3 | Manchester City FC | 2 | 0 | 1 | 0 | 0 | 0 | 1 | 0 | 1 | 1 | 1 | 3 | -2 | 1 |
| 4 | Villarreal CF | 2 | 0 | 0 | 1 | 0 | 0 | 1 | 0 | 0 | 2 | 0 | 4 | -4 | 0 |
| Wednesday September 14 | ||||
| 20:45 | Manchester City | 1 - 1 | Napoli | Etihad Stadium, Manchester |
| Goals | Kolarov 75’ | Cavani 69’ | ||
| 20:45 | Villarreal CF | 0 - 2 | Bayern Munich | El Madrigal, Villarreal |
| Goals | Kroos 6’ Rafinha’76 | |||
| Tuesday September 27 | ||||
| 20:45 | Bayern Munich | 2 - 0 | Manchester City | Allianz-Arena, Munich |
| Goals | Gomez 38’45’ | |||
| 20:45 | Napoli | 2 - 0 | Villarreal CF | Stadio San Paolo, Naples |
| Goals | Hamsik 14’Cavani17’ | |||
| Tuesday October 18 | ||||
| 20:45 | Manchester City | v | Villarreal CF | Etihad Stadium, Manchester |
| 20:45 | Napoli | v | Bayern Munich | Stadio San Paolo, Naples |
| Wednesday November 2 | ||||
| 20:45 | Villarreal CF | v | Manchester City | El Madrigal, Villarreal |
| 20:45 | Bayern Munich | v | Napoli | Allianz-Arena, Munich |
| Tuesday November 22 | ||||
| 20:45 | Bayern Munich | v | Villarreal CF | Allianz-Arena, Munich |
| 20:45 | Napoli | v | Manchester City | Stadio San Paolo, Naples |
| Wednesday December 7 | ||||
| 20:45 | Villarreal CF | v | Napoli | El Madrigal, Villarreal |
| 20:45 | Manchester City | v | Bayern Munich | Etihad Stadium, Manchester |
